Latitudinal and downcore (0–750 ka) changes in n-alkane chain lengths in the eastern equatorial Pacific     

Keiji Horikawa  Masafumi Murayama  Masao Minagawa  Yoshihisa Kato  Takuya Sagawa 《Quaternary Research》2010,73(3):573-582

The n-alkane C₃₁/(C₂₉ + C₃₁) ratios from surface sediments in the eastern equatorial Pacific (EEP) exhibit higher values to the north and lower values to the south across the southern edge (2–4°N) of the Intertropical Convergence Zone (ITCZ). Since plants tend to synthesize longer chain length n-alkanes in response to elevated temperature and/or aridity, the higher C₃₁/(C₂₉ + C₃₁) ratios at northern sites suggest a higher contribution of vegetation under hot and/or dry conditions. This is consistent with the observation that northern sites receive higher levels of plant waxes transported by northeasterly trade winds from northern South America, where hot and dry conditions prevail. Furthermore, from a sediment core covering the past 750 ka (core HY04; 4°N, 95°W) we found that C₃₁/(C₂₉ + C₃₁) ratios exhibit a long-term decrease from MIS (marine oxygen isotope stage) 17 to 13. During this period, the zonal SST (sea-surface temperature) gradient in the equatorial Pacific increased, suggesting an increase in Walker circulation. Such intensified Walker circulation may have enhanced moisture advection from the equatorial Atlantic warm pool to the adjacent northern South America, causing arid regions in northern South America to contract, which may explain long-term decrease in n-alkane chain lengths.  相似文献   

Impact of in-consistency between the climate model and its initial conditions on climate prediction     

Liu  Xueyuan  Köhl  Armin  Stammer  Detlef  Masuda  Shuhei  Ishikawa  Yoichi  Mochizuki  Takashi 《Climate Dynamics》2017,49(3):1061-1075

We investigated the influence of dynamical in-consistency of initial conditions on the predictive skill of decadal climate predictions. The investigation builds on the fully coupled global model “Coupled GCM for Earth Simulator” (CFES). In two separate experiments, the ocean component of the coupled model is full-field initialized with two different initial fields from either the same coupled model CFES or the GECCO2 Ocean Synthesis while the atmosphere is initialized from CFES in both cases. Differences between both experiments show that higher SST forecast skill is obtained when initializing with coupled data assimilation initial conditions (CIH) instead of those from GECCO2 (GIH), with the most significant difference in skill obtained over the tropical Pacific at lead year one. High predictive skill of SST over the tropical Pacific seen in CIH reflects the good reproduction of El Niño events at lead year one. In contrast, GIH produces additional erroneous El Niño events. The tropical Pacific skill differences between both runs can be rationalized in terms of the zonal momentum balance between the wind stress and pressure gradient force, which characterizes the upper equatorial Pacific. In GIH, the differences between the oceanic and atmospheric state at initial time leads to imbalance between the zonal wind stress and pressure gradient force over the equatorial Pacific, which leads to the additional pseudo El Niño events and explains reduced predictive skill. The balance can be reestablished if anomaly initialization strategy is applied with GECCO2 initial conditions and improved predictive skill in the tropical Pacific is observed at lead year one. However, initializing the coupled model with self-consistent initial conditions leads to the highest skill of climate prediction in the tropical Pacific by preserving the momentum balance between zonal wind stress and pressure gradient force along the equatorial Pacific.

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Geochemical behavior of rare earth elements in hydrothermally altered rocks of the Kuroko mining area,Japan     

N. Shikazono  Y. Ogawa  M. Utada  D. Ishiyama  T. Mizuta  N. Ishikawa  Y. Kubota 《Journal of Geochemical Exploration》2008

In this study we analyzed the chemical composition of hydrothermally altered dacite and basalt from the Kuroko mining area, northeastern Honshu, Japan, by REE (rare earth element). Features of rare earth element analyses include: (1) altered footwall dacite exhibits a negative Eu anomaly compared with fresh dacite, suggesting preferential removal of Eu²⁺ from the altered dacite via hydrothermal solutions, (2) altered hangingwall dacite and basalt and dacite and basalt adjacent to ore deposits exhibit positive Eu anomalies compared with fresh dacite and basalt, suggesting addition of Eu²⁺ from hydrothermal solutions, (3) LREE ratio (∑LREE/∑REE) from altered dacite of chlorite–sericite zone and K-feldspar zone show a negative relationship with δ¹⁸O, and La/Sm ratios show a positive correlation with the K₂O index. These trends indicate the addition of light rare earth elements such as La to the altered dacite from hydrothermal solution and/or leaching of heavy rare earth elements such as Sm and Yb, (4) Principal component analysis (PCA) indicates that light rare earth elements enrichment is related to the formation of sericite zone near the Kuroko deposits but not to the formations of chlorite and K-feldspar zones, and (5) The correlations among REE features (LREE ratio, MREE ratio, HREE ratio, Eu/Eu?), δ¹⁸O and K₂O index are not found for montmorillonite zone, mixed layer clay mineral zone and mordenite zone. Therefore, it is inferred that sericite, chlorite and K-feldspar alterations are related to the Kuroko and vein-type mineralization, but montmorillonite and mordenite alterations are not related to the mineralizations, and probably they formed at the post-mineralization stage.  相似文献   

Response of a phytoplankton community to nutrient addition under different CO2 and pH conditions     

Takeo Hama  Tomoki Inoue  Risa Suzuki  Hiroto Kashiwazaki  Shigeki Wada  Daisuke Sasano  Naohiro Kosugi  Masao Ishii 《Journal of Oceanography》2016,72(2):207-223

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N2 fixation variability in the oligotrophic Sulu Sea, western equatorial Pacific region over the past 83 kyr     

Keiji Horikawa  Masao Minagawa  Yoshihisa Kato  Masafumi Murayama  Seiya Nagao 《Journal of Oceanography》2006,62(4):427-439

N₂ fixation is an important biological process that adds new nitrogen to oceans and plays a key role in modulating the oceanic nitrate inventory. However, it is not known how, when, and where N₂ fixation rates have varied in response to past climate changes. This study presents a new record of nitrogen isotopic composition (δ¹⁵N) over the last 83 kyr from a sediment core (KH02-4 SUP8) taken in the Sulu Sea in the western equatorial Pacific region; data allow the N₂ fixation variability in the sea to be reconstructed. Sediments, sinking, and suspended particulate organic matter (POM) all have lighter isotopic values compared to the δ¹⁵N values of substrate nitrate (av. 5.8‰) in North Pacific Intermediate Water. These lighter δ¹⁵N values are regarded as reflecting N₂ fixation in the Sulu Sea surface water. A δ¹⁵N mass balance model shows that N₂ fixation rates were significantly enhanced during 54–34 kyr in MIS-3 and MIS-2. It has been speculated that higher interglacial denitrification rates in the Arabian Sea and the eastern tropical Pacific would have markedly decreased the global oceanic N inventory and contributed to the increase in N₂ fixation in oligotrophic regions, but such a model was not revealed by our study. It is possible that changes in N₂ fixation rates in the Sulu Sea were regional response, and accumulation of phosphate in the surface waters due to enhanced monsoon-driven mixing is thought to have stimulated enhancements of N₂ fixation during MIS-3 and MIS-2.  相似文献   

Behavior of heavy metals and particulate matters in seawater expected from that of radioactive nuclides     

Shizuo Tsunogai  Yoshiyuki Nozaki  Masao Minagawa 《Journal of Oceanography》1974,30(6):251-259

Vertical profiles of²¹⁰Pb and²³⁰Th in the deep water were analyzed by using a simple one-dimensional model. Both nuclides are considered to settle down with the velocity of 1×10^–4 cm/sec. The diameter of particle corresponding to the velocity is calculated to be 5, while only about 10 % of the nuclides can be collected on filter paper with a pore size of 0.5. It is supposed that the nuclides exist in particulate materials which is changeable in size. This suggestion is supported from the following evidences. (1) The directly observed behavior of marine snow and the size distribution of particles observed with a coulter counter. (2) The existence of many chemical elements of which residence time is about 150 years. (3) Their possible existence as eutectic solid phases in the seawater. (4) The consistency of the observed accumulation rate of pelagic sediments with that estimated from the settling velocity. (5) The consistency of the decomposition rate of organic matter in the deep water estimated from the oxygen comsumption with that from the settling velocity.  相似文献   

Path Transition of the Kuroshio Due to Mesoscale Eddies: A Two-Layer, Wind-Driven Experiment   总被引：1，自引：0，他引：1  

Kazunori Akitomo  Masao Kurogi 《Journal of Oceanography》2001,57(6):735-741

We have executed numerical experiments using a two-layer, wind-driven ocean model with simplified coastal geometry and bottom topography to investigate the possibility of the Kuroshio path transition due to mesoscale eddies. A straight path easily changes into a meandering path due to the eddy action. For this transition, an anticyclonic eddy is preferable to a cyclonic one when imposed in the beginning region of the Kuroshio (east of Taiwan). When imposed southeast of Kyushu, on the other hand, a cyclonic eddy is more effective than an anticyclonic one. The reverse transition, from a meandering to a straight path, did not occur at all in this experiment. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Formation, Distribution and Volume Transport of the North Pacific Intermediate Water Studied by Repeat Hydrographic Observations     

Takashi Miyao  Koichi Ishikawa 《Journal of Oceanography》2003,59(6):905-919

In order to examine the formation, distribution and transport of North Pacific Intermediate Water (NPIW), repeated hydrographic observations along several lines in the western North Pacific were carried out in the period from 1996 to 2001. NPIW formation can be described as follows: (1) Oyashio water extends south of the Subarctic Boundary and meets Kuroshio water in intermediate layers; (2) active mixing between Oyashio and Kuroshio waters occurs in intermediate layers; (3) the mixing of Oyashio and Kuroshio waters and salinity minimum formation around the potential density of 26.8σ_θ proceed to the east. It is found that Kuroshio water flows eastward even in the region north of 40°N across the 165°E line, showing that Kuroshio water extends north of the Subarctic Boundary. Volume transports of Oyashio and Kuroshio components (relative to 2000 dbar) integrated in the potential density range of 26.6–27.4σθ along the Kuroshio Extension across 152°E–165°E are estimated to be 7–8 Sv (10⁶ m³s⁻¹) and 9–10 Sv, respectively, which is consistent with recent work. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

On the distribution of isothermal layers in the vicinity of the shoal,Kokushô-sone     

Masao Fukasawa 《Journal of Oceanography》1983,39(1):15-21

Data from XBT observations in the vicinity of the shoal, Kokushô-sone (30°00′N, 128°30′E) which is located in the current zone of the Kuroshio in the East China Sea, are analysed to show the distribution of isothermal layers. Isothermal layers are found in abundance in and near a cold water region along the slope of the shoal where the existence of upwelling is suggested. It is found that there is a good spatial correlation between the distribution of isothermal layers and that of cold waters along the slope, and that the distribution of isothermal layers is a helpful indicator for elucidating the nature of oceanic structures in the vicinity of the shoal.  相似文献   

Tidal Mixing in the Kuril Straits and Its Impact on Ventilation in the North Pacific Ocean     

Tomohiro Nakamura  Takahiro Toyoda  Yoichi Ishikawa  Toshiyuki Awaji 《Journal of Oceanography》2004,60(2):411-423

A numerical study using a 3-D nonhydrostatic model has been applied to baroclinic processes generated by the K ₁ tidal flow in and around the Kuril Straits. The result shows that large-amplitude unsteady lee waves are generated and cause intense diapycnal mixing all along the Kuril Island Chain to levels of a maximum diapycnal diffusivity exceeding 10³ cm²s⁻¹. Significant water transformation by the vigorous mixing in shallow regions produces the distinct density and potential vorticity (PV) fronts along the Island Chain. The pinched-off eddies that arise and move away from the fronts have the ability to transport a large amount of mixed water (∼14 Sv) to the offshore regions, roughly half being directed to the North Pacific. These features are consistent with recent satellite imagery and in-situ observations, suggesting that diapycnal mixing within the vicinity of the Kuril Islands has a greater impact than was previously supposed on the Okhotsk Sea and the North Pacific. To examine this influence of tidal processes at the Kurils on circulations in the neighboring two basins, another numerical experiment was conducted using an ocean general circulation model with inclusion of tidal mixing along the islands, which gives a better representation of the Okhotsk Sea Mode Water than in the case without the tidal mixing. This is mainly attributed to the added effect of a significant upward salt flux into the surface layer due to tidal mixing in the Kuril Straits, which is subsequently transported to the interior region of the Okhotsk Sea. With a saline flux into the surface layer, cooling in winter in the northern part of the Okhotsk Sea can produce heavier water and thus enhance subduction, which is capable of reproducing a realistic Okhotsk Sea Mode Water. The associated low PV flux from the Kuril Straits to the open North Pacific excites the 2nd baroclinic-mode Kelvin and Rossby waves in addition to the 1st mode. Interestingly, the meridional overturning in the North Pacific is strengthened as a result of the dynamical adjustment caused by these waves, leading to a more realistic reproduction of the North Pacific Intermediate Water (NPIW) than in the case without tidal mixing. Accordingly, the joint effect of tidally-induced transport and transformation dominating in the Kuril Straits and subsequent eddy-transport is considered to play an important role in the ventilation of both the Okhotsk Sea and the North Pacific Ocean. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献